Prinsell, M., D. Everson, and D. Weix. Nickel-Catalyzed, Sodium Iodide-Promoted Reductive Dimerization of Alkyl Halides, Alkyl Pseudohalides, and Allylic Acetates. no. 31, Chem. Commun., 5745.
|Keywords||aryl halides, bond formation, bromides, chlorides, cross-couplings, dimers, electrophiles, grignard-reagents, pinacol coupling reaction, signal-transduction|
|Abstract||The first general method for the reductive dimerization of alkyl halides, alkyl mesylates, alkyl trifluoroacetates, and allylic acetates is reported which proceeds with low catalyst loading (0.5 to 5 mol%), generally high yields (80% ave yield), and good functional-group tolerance.|
|Short Title||Chem. Commun.|